dc.contributor.author | Demirhan, F; Yildirim, O; Cetinkaya, B | |
dc.date.accessioned | 2020-07-01T08:52:37Z | |
dc.date.available | 2020-07-01T08:52:37Z | |
dc.date.issued | AUG | |
dc.date.issued | 2003 | |
dc.identifier.uri | http://hdl.handle.net/20.500.12481/10089 | |
dc.description.abstract | 1-Ferrocenylmethyl-3-benzylimidazolidinium iodide and 1-ferrocenylmethyl-3-( 2,4,6-trimethylbenzyl) imidazolidinium iodide were prepared in good yields by boiling, under reflux, a solution of (ferrocenylmethyl)trimethylammonium iodide and the appropriate N-alkyl-2-imidazoline in MeCN. From the 1-ferrocenylmethyl-3-ben-zylimidazolidinium iodide salt, N-heterocylic carbene complexes of Pd-II and Rh-I were synthesized by in situ deprotonation and subsequent trapping. The new compounds were characterized by C, H, N analyses, H-1- n. m. r., C-13-n.m.r. and by cyclic voltammetry. The n. m. r. properties of the complexes are compared with those of nonferrocenylated carbene derivatives. The c. v.'s of these compounds show a number of resolved redox processes, indicating that CH(2)Fc substituents are electronically isolated from the remaining molecular framework. | |
dc.title | N-Heterocyclic carbene complexes of palladium(II) and rhodium(I) with pendant ferrocenylmethyl groups: synthesis and electrochemistry | |
dc.title.alternative | TRANSITION METAL CHEMISTRY | |
dc.identifier.DOI-ID | 10.1023/A:1025034231785 | |
dc.identifier.volume | 28 | |
dc.identifier.issue | 5 | |
dc.identifier.startpage | 558 | |
dc.identifier.endpage | 562 | |
dc.identifier.issn/e-issn | 0340-4285 | |
dc.identifier.issn/e-issn | 1572-901X | |